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I've worn skins on the Camino, the VdlP, and the coast-to-coast across England. If the weather's fine I wear light hiking trousers on top; if it's wet, I wear waterproofs. The skins reduce leg fatigue generally, which can have more specific muscle benefits, and they keep you warm. I think...
Grayland is spot-on regarding the unsuitability of jeans. I'd also suggest you should add a good quality poncho - it's almost certain to rain at some stage, especially in Galicia - and a hat with a brim that will protect you from both sun and rain. Buen Camino, wes.
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