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The distances between accommodation will vary, it's mainly in the villages although there are some agriturismo places between villages. If your guidebook doesn't provide enough detail, it's worth considering getting a copy of the Terre di Mezzo book which has the latest accommodation...
To be honest, while the signage is good, we couldn't be sure how it would be going south to north. However, if you have the guidebook and use their GPS tracks, it shouldn't be a problem. We highly recommend allowing some time in Palermo and Agrigento. Big apologies for the delayed response.
Walking the Magna Via Francigena, we journey from coast to coast, crossing Sicily from Palermo to Agrigento. Over nine days we walk 185 kms (121 mi) following old pilgrim ways and the web of transhumance paths that once covered Sicily.
https://our-wanderlust.com/2023/06/magna-via-francigena/
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