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You have 2 options.
First one is to get from Santander airport to center, all the details here (Hicantabria)
Then you have a couple of choices:
- Bus from Santander to Oviedo with ALSA, details here (ALSA)
- A long RENFE train, slower but maybe you can enjoy the ride, not recommended but just in...
I would definitely do as suggested above.
First from Airport to Santander Center, more details here
Then an ALSA Bus to Burgos, more details here
Finally from Burgos to Santo Domingo with Jimenez Movilidad (Sorry Spanish), more info here
I hope this helps!
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