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I walked the Camino from Irun to Burgos and then on to Santiago. My boots were Teva e-vent and reckon they fit your requirements. Big toe box, very light weight, strong and supportive. Not sure about waterproofing as they are not goretex - a disaster in warm weather - but I am sure you can...
There is only one kind of sock worth having and that is merino wool. Bridgedale offer the best selection from lightweight to heavyweight - look for merino wool fusion. In the end you cannot beat a sheep no matter what anyone may tell you.
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