Transport from SdC on a Sunday

Izak and Lila said:

How far can we book in advance on trains, busses

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About 60 days. For planes, you should be able to book now. Try Iberia Airlines.

As for buses and trains, they are not a good way to get to Toulouse from Santiago. For centuries Spain has obstructed access from Europe to prevent invasion. The train track gauge changes at Irun/Hendaye so that you have to walk a few meters when you take a train. High speed trains from Barcelona were added just a few years ago, so you can go around the Pyrenees that direction to Toulouse now. It takes a while, is not really "cheap," but is quite comfortable. You probably will have a train change after Barcelona, but it is a good opportunity to try French coffee after a month of Spanish coffee. I defer on which is better!

Izak and Lila said:

We are finding difficulty with all transport [train, bus or air], out of Santiago on Sunday 14 October 2018 to Toulouse. How far can we book in advance on trains, busses or flying out of Santiago?

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06,40 - IBERIA via Madrid
09,20 - IBERIA via Madrid
10,15 - Vueling via Barcelona
13,20 - IBERIA via Madrid

Wish you well , Peter .

Izak and Lila said:

We are finding difficulty with all transport [train, bus or air], out of Santiago on Sunday 14 October 2018 to Toulouse. How far can we book in advance on trains, busses or flying out of Santiago?

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You could fly EasyJet to Geneva (SDC at 0915 ; GVA at 1115) with a flight to Toulouse at 1225 ; I have never used Geneva Airport so I would not be sure about such a tight connection but probably feasible with hand-luggage only. Flights are on sale at this moment at very sensible prices.

If the transfer time is a concern, you could spend a night in Geneva with another choice being an overnight in Basel (also with EJ) though the flight to Basel is expensive.

Good luck.